Chemical Product and Company Identification
Product/Chemical Name: Sorbic Acid
Chemical Formula: C6H8O2
CAS Number: 110-44-1
Other Designations: 2,4-Hexadienoic Acid
Derivation:
General Use:
Emergency Telephone: 1-800-424-9300 (Chemtrec)
Section 2 - Composition / Information on Ingredients
Ingredient Name |
CAS Number |
EINECS/ELINCS |
% wt or % vol |
Sorbic Acid |
110-44-1 |
203-768-7 |
98 |
Trace Impurities:
|
OSHA PEL |
ACGIH TLV |
NIOSH REL |
NIOSH |
Ingredient |
TWA |
STEL |
TWA |
STEL |
TWA |
STEL |
IDLH |
Sorbic Acid |
none estab. |
none estab. |
none estab. |
none estab. |
none estab. |
none estab. |
none estab. |
Section 3 - Hazards Identification
Emergency Overview
CAUTION! CAUSES IRRITATION.
: : :
HMIS |
H
F
R |
0
1
1 |
PPE†
†Sec. 8 |
Potential Health Effects
Primary Entry Routes: Inhalation, ingestion and skin contact.
Target Organs:
Acute Effects
Inhalation:
Eye: Irritation.
Skin: Irritation.
Ingestion:
Carcinogenicity: IARC, NTP, and OSHA do not list Sorbic Acid as a carcinogen.
Medical Conditions Aggravated by Long-Term Exposure: No information found.
Chronic Effects: No information found.
Section 4 - First Aid Measures
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Prompt action is essential.
Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.
Skin Contact: In case of contact, flush skin with water.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
After first aid, get appropriate in-plant, paramedic, or community medical support.
Note to Physicians:
Special Precautions/Procedures:
Section 5 - Fire-Fighting Measures
Flash Point: 127 °C (261°F)
Flash Point Method: CC
Burning Rate:
Autoignition Temperature:
LEL: not available
UEL: not available
Flammability Classification: low
Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Unusual Fire or Explosion Hazards: none known
Hazardous Combustion Products:
Fire-Fighting Instructions: Do not release runoff from fire control methods to sewers or waterways.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full facepiece operated in pressure-demand or positive-pressure mode.
Section 6 - Accidental Release Measures
Spill /Leak Procedures: Wear self-contained breathing apparatus and full protective clothing.
Spills: With clean shovel, carefully place material into clean, dry container and cover; remove from area.
Large Spills
Containment: For large spills, dike far ahead of spill for later disposal. Do not release into sewers or waterways.
Cleanup: Flush spill area with water.
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
Section 7 - Handling and Storage
Handling Precautions/ Storage Requirements: Do not store near oxidizing materials. Keep container tightly closed. Store in a cool, dry, well-ventilated area. Store in light-resistant containers. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls:
Ventilation: Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs (Sec. 2). Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source.
Administrative Controls:
Respiratory Protection: Seek professional advice prior to respirator selection and use. Follow OSHA respirator regulations (29 CFR 1910.134) and, if necessary, wear a MSHA/NIOSH-approved respirator. Select respirator based on its suitability to provide adequate worker protection for given working conditions, level of airborne contamination, and presence of sufficient oxygen. For emergency or non-routine operations (cleaning spills, reactor vessels, or storage tanks), wear an SCBA. Warning! Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. If respirators are used, OSHA requires a written respiratory protection program that includes at least: medical certification, training, fit-testing, periodic environmental monitoring, maintenance, inspection, cleaning, and convenient, sanitary storage areas.
Protective Clothing/Equipment: Wear chemically protective gloves, boots, aprons, and gauntlets to prevent prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection regulations (29 CFR 1910.133). Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses.
Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area.
Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse. Remove this material from your shoes and clean personal protective equipment.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics.
Section 9 - Physical and Chemical Properties
Physical State: solid
Appearance and Odor: White crystalline powder
Odor Threshold:
Vapor Pressure: 0.01 mm Hg at 20 °C
Vapor Density (Air=1):
Formula Weight: 112.13
Density:
Specific Gravity (H2O=1, at 4 °C): 3.87
pH: |
Water Solubility: slightly soluble
Other Solubilities:
Boiling Point: 228 °C (442 °F)
Freezing/Melting Point: 134 °C (273 °F)
Viscosity:
Refractive Index:
Surface Tension:
% Volatile: 0
Evaporation Rate:
|
Section 10 - Stability and Reactivity
Stability: Sorbic Acid is stable at room temperature in closed containers under normal storage and handling conditions.
Polymerization: Hazardous polymerization will not occur.
Chemical Incompatibilities: Strong oxidizing agents.
Conditions to Avoid: Incompatibilities, Heat, Light.
Hazardous Decomposition Products: Thermal oxidative decomposition of Sorbic Acid can produce carbon monoxide, carbon dioxide.
Section 11- Toxicological Information
Toxicity Data:*
IRRITATION DATA
SKN-MAN 150 MG/1H SEVERE
SKN-RBT 1 MG SEVERE |
Acute Oral Effects:
Rat, oral, LD50: 7360 mg/kg
Chronic Effects:
Carcinogenicity:
Mutagenicity:
Teratogenicity: |
See NIOSH, RTECS (WG2100000), for additional toxicity data.
Section 12 - Ecological Information
Ecotoxicity: no information found.
Environmental Fate: no information found.
Environmental Degradation:
Soil Absorption/Mobility:
Section 13 - Disposal Considerations
Disposal: Contact your supplier or a licensed contractor for detailed recommendations. Follow applicable Federal, state, and local regulations.
Section 14 - Transport Information
DOT Transportation Data (49 CFR 172.101): Not regulated
Shipping Name:
Shipping Symbols:
Hazard Class:
ID No.:
Packing Group:
Label:
Special Provisions (172.102): |
Packaging Authorizations
a) Exceptions:
b) Non-bulk Packaging:
c) Bulk Packaging: |
Quantity Limitations
a) Passenger, Aircraft, or Railcar:
b) Cargo Aircraft Only:
Vessel Stowage Requirements
a) Vessel Stowage:
b) Other: |
Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 110-44-1 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 110-44-1: acute.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
2,4-Hexadienoic acid is not present on state lists from CA, PA, MN,MA, FL, or NJ.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 4/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 45 In case of accident of if you feel unwell, seek medical advice immediately (show the label where possible).
S 28B After contact with skin, wash immediately with plenty of water and soap.
WGK (Water Danger/Protection)
CAS# 110-44-1: 0
Canada
CAS# 110-44-1 is listed on Canada's DSL/NDSL List.
This product has a WHMIS classification of D2B, F.
CAS# 110-44-1 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
Section 16 - Other Information
Disclaimer: All information, recommendations and suggestions appearing herein are based upon sources believed to be reliable: However, it is the users responsibility to determine the safety, toxicity and suitability for its own use of this product. Federated Mills, Inc. DOES NOT ASSUME ANY LIABILITY ARISING OUT OF THE USE BY OTHERS OF THIS PRODUCT.